Application of Inelastic Neutron Scattering to the Methanol-to-Gasoline Reaction Over a ZSM-5 Catalyst

نویسندگان

  • Russell F. Howe
  • James McGregor
  • Stewart F. Parker
  • Paul Collier
  • David Lennon
چکیده

Inelastic neutron scattering (INS) is used to investigate a ZSM-5 catalyst that has been exposed to methanol vapour at elevated temperature. In-line mass spectrometric analysis of the catalyst exit stream confirms methanol-to-gasoline chemistry, whilst ex situ INS measurements detect hydrocarbon species formed in/on the catalyst during methanol conversion. These preliminary studies demonstrate the capability of INS to complement infrared spectroscopic characterisation of the hydrocarbon pool present in/on ZSM-5 during the MTG reaction.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Selective Synthesis of Gasoline-Ranged Hydrocarbons from Syngas over Hybrid Catalyst Consisting of Metal-Loaded ZSM-5 Coupled with Copper-Zinc Oxide

The conversion of syngas (CO + H2) to gasoline-ranged hydrocarbons was carried out using a hybrid catalyst consisting of metal-loaded ZSM-5 coupled with Cu-ZnO in a near-critical n-hexane solvent. Methanol was synthesized from syngas over Cu-ZnO; subsequently, was converted to hydrocarbons through the formation of dimethyl ether (DME) over the metal-loaded ZSM-5. When 0.5 wt% Pd/ZSM-5 and 5 wt%...

متن کامل

Conversion of Methanol to Hydrocarbons over Ni-zsm-5 Catalyst

As stock of crude oil is limited, new resources for fuel and petrochemicals are required to be developed. Natural gas or biogas can be easily converted into methanol which can be converted into gasoline and olefins. This study uses zeolite catalyst (ZSM-5) and its modification by Ni to convert methanol to hydrocarbons (MTH). Catalysts are studied at different temperatures and at different loadi...

متن کامل

Catalytic Conversion of Methanol to Hydrocarbons over different wt% Ni-HZSM-5

Due to crude oil is limited, new resources for fuel and petrochemicals are important to be developed. Biogas or NG (Natural Gas) can be easily converted into methanol which can be reacted over zeolite to produce olefins and gasoline. HZSM-5 zeolite catalyst has been used in this study and its modification by (0.5wt%, 1wt%, 2wt% and 4wt %) Ni to convert methanol to hydrocarbons (MTH). Catalysts ...

متن کامل

An assessment of hydrocarbon species in the methanol-to-hydrocarbon reaction over a ZSM-5 catalyst.

A ZSM-5 catalyst is examined in relation to the methanol-to-hydrocarbon (MTH) reaction as a function of reaction temperature and time-on-stream. The reaction profile is characterised using in-line mass spectrometry. Furthermore, the material contained within a catch-pot downstream from the reactor is analysed using gas chromatography-mass spectrometry. For a fixed methanol feed, reaction condit...

متن کامل

Methanol-to-Hydrocarbons Product Distribution over SAPO-34 and ZSM-5 Catalysts: The applicability of Thermodynamic Equilibrium and Anderson-Schulz-Flory Distribution

The product distribution of methanol to hydrocarbons conversion over SAPO-34 and ZSM-5 catalysts was studied using thermodynamic equilibrium and Anderson-Schulz-Flory (ASF) distributions. The equilibrium compositions were calculated using constrained Gibbs free energy minimization. The effect of catalyst type was considered by setting upper limits to product carbon number due to sh...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2016